Contrast between metamorphic and ore-forming fluids in the Ailaoshan belt, southeastern Tibet: New constraints on ore-fluids source for its orogenic gold deposits

Abstract

The source of ore-forming fluids for orogenic gold deposits is still disputed with models ranging from derivation from metamorphism of continental crust to derivation from metasomatized mantle lithosphere. This dispute is addressed by this study of the Ailaoshan orogenic gold belt, southeastern Tibet, whose evolution involved intense metamorphism on the eastern side of the Ailaoshan shear zone. Both the regional metamorphic barren quartz veins and gold-related quartz veins in this belt are genetically related to movement on the Ailaoshan shear zone and thus formed over the same limited age span. Microthermometry, fluid compositions and stable isotope analyses conducted on both metamorphic fluids extracted from regional metamorphic quartz veins and ore-forming fluids collected from auriferous quartz veins at Zhenyuan and Jinchang gold deposits reveal significant differences. These include: (1) regional metamorphic quartz veins contain three types of fluid inclusions, including CO2-rich, aqueous-CO2 and aqueous types. The CO2-bearing inclusion types are more abundant than those in auriferous quartz veins; (2) those fluids from barren metamorphic veins with high CO2 content (up to 45 mol%) are typified by low-medium temperature (217–418 °C), low salinity (2–8 wt% NaCl) and variable pressure (28–440 MPa), and belong to the NaCl-CO2-H2O system. In contrast, the ore-forming fluids, which exhibit lower temperature (mainly 170–270 °C), higher salinity (mainly 5–13 wt% NaCl), and lower pressure (20–282 MPa and 14–44 MPa for Zhenyuan and Jinchang, respectively), belong to the NaCl-H2O-CO2 system; (3) the metamorphic fluids contain high Ca2+ and Mg2+ in liquids and CO2, N2 and CO in gases, whereas the ore-forming fluids are enriched in K+ in liquid and H2O, CO2, CH4 in gases; (4) the pyrites from regional metamorphic quartz veins have δ34S values ranging from 2.08 to 2.86‰ (mean = 2.50‰), indicating a single sulfur source of metamorphic fluids, thus contrasting with the broad range of δ34S values of ore sulfides. These distinctions negate a genetic relationship between crustal metamorphism and gold mineralization and demonstrate that ore-fluids that deposit orogenic gold deposits, at least in the Ailaoshan belt cannot be derived or evolved from crustally-derived regional metamorphic fluids. This provides a new line of evidence for the derivation of ore-forming fluids from a sub-crustal, metasomatized mantle lithosphere source for at least some orogenic gold deposits.