Abstract

The primary goals of this study were to reveal the environmental status of potentially toxic elements (PTEs) and their ecological risks, as well as their associated health risks in the Baoshan area, southwest China, which has been surveyed with the scale of 1:250,000 geochemical mapping. Based on a comparison of the PTE concentrations with the soil environmental quality of China and the enrichment factor (EF), geo-accumulation index (Igeo), contamination factor (Cf), and potential ecological risk indexes (Eri and PERI), as well as the potential non-carcinogenic hazard indices (HI and CHI) and carcinogenic risks indices (TCR and CTCR), the following conclusions were drawn: The PTE concentrations in the surface soil samples that were collected from the investigated area (1.65% sites) exceeded the risk intervention values (RIV) for soil contamination of agricultural land of China. Cadmium (Cd) and mercury (Hg) posed higher ecological risks than other PTEs (arsenic (As), chromium (Cr), lead (Pb), copper (Cu), nickel (Ni), and zinc (Zn)), which was highlighted by their toxic response factor. Arsenic was the main PTE with a non-carcinogenic risk (19.57% sites for children and 0.25% sites for adults) and the only PTE that carries a carcinogenic risk (2.67% sites for Children and 0.76% sites for adults) to humans in the research area. Children are more vulnerable to health risks when compared to adults because of their behavioral and physiological traits. Geological genesis was responsible for the high concentrations, ecological risk, and health risk distribution patterns of the examined PTEs. Even though the present research highlights several important aspects related to PTE pollution in the research area, further investigations are needed, especially in mining areas.

Highlights

  • Soil is the foundation of food production systems and is a critical component for national food security

  • Certain indicators have been used in environmental studies on potentially toxic elements (PTEs) in soil to assess the severity of pollution, potential ecological risk, and potential health risks to human beings that they cause [70,71,72]

  • The potential ecological risk (Eri ) of a given PTE and the potential ecological index (PERI), which indicates the sum of potential ecological risks, are commonly employed at the regional and/or global levels to assess the potential impact of the pollutants in soil on ecosystems [72]

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Summary

Introduction

Soil is the foundation of food production systems and is a critical component for national food security. The PTE levels in soil are frequently elevated due to mineral resources (such as Cu, Pb, Zn, and Hg), as well as carbonate and basalt parent materials [56,57,58,59,60,61,62,63]. This phenomenon can be observed in the soils of the Baoshan area in Yunnan province, southwest. Zn) pollution levels in the soil; (2) assess the ecological risk of PTEs in soil and their health risks to humans; (3) map the risk level distribution to allow direct appraisal; and (4) make recommendations to authorities and environmental protection agencies

Study Area
Pollution Estimation and Risk Assessment
Pollution Evaluation Indicators
Ecological Risk Assessment
Human Health Risk Assessment
Data Statistical Analysis and Mapping
Concentration of PTEs in Soils of the Study Area
Comparison to National Agricultural Land Risk Control Standard Values
Evaluation by Pollution Indices
Assessing the Environmental Ecological Risks of the Surface Soil
Non-Carcinogenic Risks to Humans
Carcinogenic Risks to Humans
Conclusions
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