Construction of antifouling zwitterionic membranes by facile multi-step integration method

Abstract

Membrane fouling during the use of separation membrane has always been the main reason for the degradation of membrane performance. The traditional solution is complicated and inefficient, so we proposed multi-step integration method to prepare antifouling zwitterionic poly(aryl ether sulfone) (PAES-Z-x) ultrafiltration (UF) membrane with higher efficiency. We designed and synthesized a bisphenol precursor containing tertiary amine groups, which could provide reactive sites for grafting zwitterionic group. Afterwards, the zwitterionic modified UF membrane was prepared by graft copolymerization and non-solvent-induced phase separation (NIPS). The morphology, hydrophilicity, water flux and rejection of the PAES-Z-x membrane could be optimized by tuning zwitterion content. The hydration layer formed by zwitterions effectively reduced the adsorption of proteins and endowed the membrane good antifouling properties. The resulting membrane showed the pure water flux increased (up to 311 L m−2h−1 bar−1), high bovine serum albumin (BSA) rejection (97%) and good water flux recovery ratio (FRR) (82.8%). Zwitterionic antifouling PAES UF membrane prepared by a simple and effective method provided a new direction for improving PAES UF membrane’s antifouling performance.