Consequences of competitive adsorption between polymers on the rheological behaviour of cement pastes

Abstract

Self Compacting Concretes (SCC) are characterized by their high fluidity so they can be placed in sections with congested reinforcements and in restricted areas without vibration. Furthermore, SCC cement paste has to be viscous enough to avoid segregation and to maintain the stability of the suspension until the onset of hardening. To fulfil these rheological requirements, mix design engineers combine use of superplasticizers and viscosity agents. The mechanism of action of these chemical admixtures is very sensitive to their adsorption. The blending of these polymers generates a competitive adsorption on surface sites of cement particles, which influences their performances. For a better understanding of competitive adsorption, we measure here both the amount of adsorbed polymers and its consequences on the rheological behaviour of the system in terms of yield stress and plastic viscosity. Our results suggest that the competitive adsorption prevents some of the polymer molecules from adsorbing, thereby moderating the performances of adsorbing polymers and enhancing the effects of polymers potentially in solution on the rheological properties of cement paste.