Utilization of coal gangue power generation industry by-product CFA in cement: Workability, rheological behavior and microstructure of blended cement paste

Abstract

Circulating fluidized bed fly ash (CFA), by-product of coal gangue power generation industry based on circulating fluidized bed combustion technology, differs from ordinary fly ash (OFA) in its physical and chemical properties. This paper aims to investigate the influences of CFA with three particle sizes on the workability and rheological properties of cement paste. The results show that untreated raw CFA (RCFA) can significantly degrade many properties of fresh cement paste. Directly using CFA as a mineral admixture in cement-based materials is not suitable in terms of workability. However, CFA through grinding methods can significantly mitigate the detrimental effect of CFA on the flowability of cement paste. When 15% ultrafine CFA (UCFA) was added, the cement paste exhibited relatively favorable workability and rheological properties. The rheological behavior of cement paste containing CFA with three particle sizes follow the shear thinning, which is in line with the modified Bingham model. Furthermore, the reasons for the impact of CFA on the microscopic level of cement workability are analyzed and discussed. The addition of CFA reduces the amount of free solution in the cement paste, leading to the formation of a flocculated structure and an increase in the thixotropic loop area. Based on the analysis of TOC, BET and TEM, it was determined that numerous polycarboxylate superplasticizer (PCE) molecules are adsorbed onto the rough and porous surface structure of CFA particles, hence the destructive ability of PCE to the flocculation structure caused by cement hydration is weakened. Therefore, the mechanism that CFA affecting the working performance of cement paste can be determined as: the adsorption of free water and PCE molecules.