Abstract
AbstractThe reaction of [Ni2(iPr2Im)4(COD)] (1) {iPr2Im = 1,3‐bis(isopropyl)imidazolin‐2‐ylidene} with hexafluorobenzene and decafluorobiphenyl results at room temperature in the formation of the products of a C–F bond activation reaction, i.e. [Ni(iPr2Im)2(F)(C6F5)] (2) and [Ni(iPr2Im)2(F)(C12F9)] (4). The reactions of 2 and 4 with 1 or the reactions of hexafluorobenzene and decafluorobiphenyl with 1 equiv. or excess of dinuclear 1 (stoichiometric ratio nickel/substrate > 2:1) at higher temperatures afford the complexes of a consecutive C–F bond‐activation reaction, [1,4‐{Ni(iPr2Im)2(F)}2(C6F4)] (3) and [4,4′‐{Ni(iPr2Im)2(F)}2(C12F8)] (5). Complexes 3 and 5 cleanly react in THF at room temperature with chlorotrimethylsilane and (isopropyl)(trimethylsilyl)selenane under elimination of fluorotrimethylsilane to yield the corresponding chloro and selenolato complexes [1,4‐{Ni(iPr2Im)2(X)}2(C6F4)] [X = Cl (6), iPrSe (7)] and [4,4′‐{Ni(iPr2Im)2(X)}2(C12F8)] [X = Cl (8), iPrSe (9)].
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