Abstract
This work elucidates the morphology-photoluminescence (PL) emission relationships, based on experimental and calculated results, on β-Ag 2 MoO 4 samples synthesized by microwave-assisted hydrothermal method. It was shown that the solvent (water and ammonia) and temperature (120, 130, 140, and 150 °C) play a crucial role in the morphology and PL emissions. A crystal structure model, composed by the local coordination of both Ag and Mo atoms at bulk and exposed surfaces, was built, and the possible mechanism along the synthesis progress was proposed and analyzed. This study provides an idea for the preparation and development of β-Ag 2 MoO 4 based materials with desirable properties.
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