Abstract

The effect sulfur dioxide has on the dynamics of the spontaneous ignition of hydrogen-oxygen mixtures is studied. Additives of SO2 have no negative effect on spontaneous ignition and undergo chemical conversion to form elemental sulfur. The results are analyzed using the theory of branched chain reactions along with data on SO2 conversion under the action of chain reactions of hydrocarbon oxidation and slow hydrogen oxidation. The transformations classified as parallel reactions from the viewpoint of formal kinetics could actually be conjugated radical-chain processes.

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