Abstract
AbstractThe spin rearrangement of π‐electrons in the ground state of a conjugated molecule in a strong magnetic field H is discussed. The spin S of the molecule increases as the field H increases (intramolecular paramagnetism). The dependence S(H) for linear and cyclic conjugated molecules in the free‐electron model and in the Hückel‐London approximation is derived. For the cyclic molecules the diamagnetic effects are taken into account.
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