Abstract
Abstract Proton NMR studies of tertiobutyl-4, D-4, thiacyclohexane, which has a fixed chair conformation, have allowed a direct determination of the various coupling constants. A discussion of the values of the ring torsion angles calculated from the different gauche constants 3 J shows that the most probable value is given by J Hαe ,H βa for which there is no hydrogen atom antiperiplanar to the S atom.
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