Confining polyacrylic acid on the surface of nanoscale zero-valent iron by aluminum hydroxide for in-situ anti-passivation

Abstract

Aggregation and surface passivation of nanoscale zero-valent iron (NZVI) particles have limited their reactivity and application for environmental remediation. In this study, an aluminum hydroxide/polyacrylic acid (Al(OH)3/PAA) hybrid shell was homogeneously coated on the NZVI surface to overcome the limitations. PAA molecules were confined onto the NZVI surface by hydration of Al(III) cations. The Al(OH)3/PAA coating shell provided more electrostatic repulsion forces between NZVI particles to hinder the particle aggregation and preserve the NZVI reactivity. On the other hand, the surface-anchored PAA provided a thickened reactive layer for Cr(VI) reduction. Besides, XPS and TEM results showed that the surface carboxylic groups bound produced Cr(III) and Fe(III) cations and inhibited the precipitation of hydroxides on the NZVI surface. The reduced passivation layer increased the longevity of NZVI for surface reactions. As a result, the 24-h Cr(VI) reduction capacity of NZVI particles was improved from 49.4 to 92.6 mg/g with a 2 wt% (Al/Fe) Al(OH)3/PAA coating shell. Overall, this study presented a promising strategy to effectively tune the surface properties of nanoparticles and improve the feasibility of NZVI for environmental remediation.