Compressive Strain in Core-Shell Au-Pd Nanoparticles Introduced by Lateral Confinement of Deformation Twinnings to Enhance the Oxidation Reduction Reaction Performance.

Abstract

In this work, quasi-spherical, uniform gold nanoparticles with rich deformation twinning (Audt NPs) were first synthesized with the assistance of copper(II) ions. Then, these Audt NPs were used as the cores for the fabrication of core-shell (CS) Audt-Pd NPs with ultrathin Pd layers, which also can bear compressive strain because of the formation of corrugated structured Pd shells led by the lateral confinement imposed by deformation twinning in the Au cores. The presence of compressive strain in the CS Audt-Pd NPs can result in the widening of the d-band width of the Pd shell and further the downshift of their d-band center, which can then improve the desorption ability of intermediates and still maintain the adsorption ability of the reactants because of the broad adsorption potential range. Taking the oxidation reduction reaction and the ethanol oxidation reaction as examples, the as-prepared Audt-Pd NPs indeed exhibited superior catalytic performances because of the synergism of compressive strain and the electronic effect. Thus, our work opens a new way to introduce compressive strain in the Pd-based CS NP catalysts, which can achieve the enhancement in the electrocatalytic performance by combining the merit of compressive strain and the electronic effect.