Comprehensive investigations into low temperature oxidation of heavy crude oil

Abstract

Due to the significance of low temperature oxidation (LTO) process on the subsequent oxidation reactions and oil recovery for in situ combustion (ISC), this work aimed at conducting a series of comprehensive investigations into LTO of heavy crude oil. The LTO behavior of heavy oil was analyzed by static oxidation experiments. Then the alterations in oil characteristics due to LTO were investigated through coke content measurements, flammability tests and scanning electron microscopic (SEM) observations. Additionally, the effect of LTO on thermal behavior and kinetics of heavy oil was researched using thermogravimetry (TG)/differential scanning calorimetry (DSC) technique. The results showed that the temperature played a crucial role in LTO of heavy oil. Almost no coke was deposited at 80 °C. The amount of coke deposition at 160 °C averaged 0.346 g coke/g oil, which was roughly 4.2 times higher than that at 120 °C. The oxidized oil at 160 °C possessed the most superior flammability at ambient temperature and atmospheric pressure in comparison to that at 80 and 120 °C. The surface morphologies of oxidized oil at 160 °C and its formed coke were quite rough, which boosted the subsequent combustion reactions. The results of TG/DSC unravelled that the oxidized oils were subjected to higher mass loss and exothermic effect at the fuel deposition (FD) and high temperature oxidation (HTO) stages as compared to crude oil. After the static LTO, the activation energy in the LTO and FD stages for heavy oil was increased, while that in the HTO stage was reduced. Compared with crude oil and oxidized oils, the coke deposited during the static LTO presented the highest thermal release and reaction activity in the HTO interval. This paper can provide some new insights regarding LTO mechanisms of heavy oil to rich the ISC technology.