Composite membrane comprised of SnO2 nanoparticles loaded intercrosslinked network of Polyvinylalcohol and Chitosan for proton transfer membrane fuel cells

Abstract

ABSTRACT In this work, an inter-crosslinked network membrane of polyvinyl alcohol (PVA) and chitosan (CS) and SnO2 nanocparticle-incorporated nanocomposite membranes of PVA and CS (PVA/CS/SnO2) having enhanced proton conductivity have been fabricated by the solvent-casting method. SnO2 nanoparticles are synthesized using a sol–gel method, and their crystalline nature, morphology and particle size are examined using X-ray diffraction analysis, scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HR-TEM), and the characteristics of the membranes such as proton conductivity (PC), swelling ratio (SR), porosity, water uptake (WU), oxidative stability (OS), ion exchange capacity (IEC), and other common physiochemical characteristics were also assessed for both the bare and SnO2 nanoparticles loaded PVA/CS films. At room temperature (RT), the highest IEC rate of 0.94 mmol g−1 and proton conductivity value of 6.3 × 10−3 S cm−1 for PVA/CS/SnO2 were observed when 3 weight percent SnO2 nanoparticles were added to PVA/CS. Additionally, the PVA/CS/SnO2 compsoite membrane loaded with 3 wt% SnO2 NPs, at 80°C for 10 hours, showed outstanding OS with 12.3% degradation towards the Fenton reagent under anhydrous conditions. As this work combines the upgrading of commodity polymers, like PVA, to be employed in fuel cell devices, the nanocomposite membranes created in this work showed notable properties that may find a large place in the future fuel cell industry.