Composite electrolyte membranes incorporating viscous copolymers with cellulose for high performance lithium-ion batteries

Abstract

A novel composite electrolyte membrane (CEM), consisting of a viscous PEGMEM-co-SMA copolymer, lithium salt and cellulose matrix, has been prepared as a new class of electrolyte for high performance lithium-ion batteries (LIBs). This CEM exhibits a wide electrochemical stability window (>5V vs. Li/Li+), reasonably high ionic conductivity and thermal stability up to 315°C. At temperature above the melting temperature (31.98–35.71°C), the viscous flow nature of the copolymer is beneficial to fully infiltrate the electrode materials like liquid electrolyte to maintain uniform contact with electrode surfaces during charge/discharge process. The interfacial resistance (Rintf ) of the fresh cell based on this CEM is extremely low (3.8Ωcm−2) and the Li/LiFePO4 cell deliveries a discharge capacity as high as 156.9mAhg−1 with a current density of 1C at 80°C. It is anticipated that this work provides a new insight for designing advanced electrolyte materials for LIBs with enhanced interfacial contact and excellent cycling performance.