Abstract

Abstract The following compounds: TlClI2 (PyO)2; TlClI2(2-PicO)2; TlClI2(3-PicO)2; TlClI2(4-PicO)2; TlClI2(4-Cl-PyO)2; TlClI2 (4-CN-PyO)2; TlClI2(4-NO2-PyO)2 and TlClI2 (4-CH3O-PyO)2 have been prepared and characterized by elemental analysis. The solids behave as monomers and non-electrolytes in solution. Possible molecular structures are given on the basis of 1H NMR and lR spectra, with particular attention on the νTl-X and νTl-O strectching modes.

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