Abstract
The oxidation of aromatic primary amines with chromyl chloride in carbon tetrachloride or chloroform, results in the formation of intermediate solid adducts (Etard adducts) which, on hydrolysis, give azobenzenes( 1), 1,4-benzoquinones( 2),anilino-1,4-benzoquinones( 3), 1,4-benzoquinone anils( 4)and anilino-1,4-benzoquinone anils ( 5) in yields which depend on the position, nature and degree of substitution of the ring.
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