Abstract
Reactions of the mixed bidentate ligands: 8-(diphenylarsino)quinoline (N-As), 8-(diphenylphosphino)quinoline (N-P), and 8-aminoquinoline (N-N) with the rhodium dimer, [Rh(CO) 2Cl] 2, were investigated. The complexes [Rh(N-As)(CO)Cl], [Rh(N-P)(CO)Cl], and [Rh(N-N)(CO) 2]Cl have been isolated and characterized. Reactions of the above ligands with iridium anion, [Ir(CO) 2Cl 2] −, gave [IrH(N-As)(CO)Cl 2], [Ir(N-P)(CO)Cl], and [Ir(N-N)(CO)Cl], respectively. Structures for the above complexes were assigned based on their IR and 1H NMR spectra, analyses, electrical conductance and molecular weight measurements.
Full Text
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