Abstract

Complexes of o-phenylenediamine with iron(II) halides have been prepared and characterized by infrared, electronic, and Mossbauer spectroscopy and magnetic susceptibility measurements. Compounds having two, three, four, and six o-phenylenediamine ligands per iron have been isolated. The complexes are all high spin. The infrared data indicate that some of the complexes involve chelated ligands and others unidentate ligands.

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