Abstract
Chromium(III) reacts only with difficulty with thioureas, giving CrL 3X 3 complexes (L = thiourea or substituted thiourea; X = halide). Such species undergo solvolysis in solvents like dimethylformamide, dimethylsulphoxide or acetonitrile; dissociation of one X − ion and one or two L ligands occurs. Electronic spectra are reported and discussed for both the CrL 3X 3 species and the solvolysis products. The spectrochemical strength of thioureas appears to be particularly low, in comparison with data on thiourea complexes of other transition metals.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
