Abstract
Titanium(III) iodide has been allowed to react with a range of ligands containing oxygen and nitrogen donor atoms, and the complexes of the following stoicheiometry isolated and characterised: 2Til3,3bipy, Til3,2L (L = ethyleneglycol dimethyl ether, trimethylamine, α-picoline, and 1,10-phenanthroline), Til3,3L (L = pyridine, γ-picoline, tetrahydrofuran, and 1,4-dioxan), and Til3,4CH3CN. Structures have been assigned to the compounds on the basis of various physical measurements, including conductivities and infrared spectra. The significance of the electronic spectra are discussed, and Dq for l– estimated at 500–600 cm.–1 with respect to titanium(III).
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of the Chemical Society A: Inorganic, Physical, Theoretical
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
