Abstract

The electronic excitation spectrum of β-CuPc has been investigated using electron energy-loss spectroscopy in transmission. Our results demonstrate a rather strong momentum dependence of the lowest exciton features. Both main components show a negative dispersion, and the momentum dependence indicates that this negative dispersion is parallel to the molecular stacks in β-CuPc. In addition, the spectral shape also varies upon increasing momentum transfer indicating a particular momentum dependence of the inter-molecular interactions.

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