Abstract
The present work is undertaken to examine the stability, and reactivity of chiral [FeIV(N2Py2Q*)(O)]2+ (N2Py2Q* = N,N.bis(2-quinolylmethyl)-1,2-di(2-pyridyl)ethylamine) complex, along with the mechanistic details of thioanisole, benzylalcohol, and hydrocarbon oxidation in comparison with [FeIV(N4Py*)(O)]2+ (N4Py* = N,N-bis(2-pyridylmethyl)-1,2-di(2-pyridyl)ethylamine) and the related achiral FeIVO systems as a test before its utilization in an enantioselective synthesis.
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