Comparison of the stability and reactivity of achiral versus chiral nonheme oxoiron(IV) complexes supported by pentadentate N5 ligands in oxygen-atom and hydrogen-atom transfer reactions

Dóra Lakk-Bogáth,Gábor Speier,József Kaizer

doi:10.1016/j.inoche.2019.107446

Comparison of the stability and reactivity of achiral versus chiral nonheme oxoiron(IV) complexes supported by pentadentate N5 ligands in oxygen-atom and hydrogen-atom transfer reactions

Dóra Lakk-Bogáth, Gábor Speier + Show 1 more

https://doi.org/10.1016/j.inoche.2019.107446

Copy DOI

Journal: Inorganic Chemistry Communications	Publication Date: Jun 18, 2019
Citations: 5

Affiliation: University of Pannonia

#Hydrogen-atom Transfer Reactions #2-pyridyl Ethylamine + Show 8 more

Abstract
Full-Text
Similar Papers

Abstract

The present work is undertaken to examine the stability, and reactivity of chiral [FeIV(N2Py2Q*)(O)]2+ (N2Py2Q* = N,N.bis(2-quinolylmethyl)-1,2-di(2-pyridyl)ethylamine) complex, along with the mechanistic details of thioanisole, benzylalcohol, and hydrocarbon oxidation in comparison with [FeIV(N4Py*)(O)]2+ (N4Py* = N,N-bis(2-pyridylmethyl)-1,2-di(2-pyridyl)ethylamine) and the related achiral FeIVO systems as a test before its utilization in an enantioselective synthesis.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Similar Papers

Paper Title

Journal

Date

Author

View more papers

More From: Inorganic Chemistry Communications

Paper Title

Journal

Date

Author

View more papers

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.