Abstract
In this paper, the solutions of three models of reaction kinetics in HV circuit breakers with SF6 after current zero are presented and compared. One model has been proposed by Bartlová, the co-author of this paper, the other two models under comparison have been taken over from the literature. In all the three models a constant pressure p(t) = 4 atm and the same dependence of temperature on time T(t) are assumed. For the description of the relation between equilibrium and kinetic composition in a system, the concept of asymptotic composition is introduced. A comparison of the composition and enthalpy of the products of SF6 dissociation and ionization for the given pressure and T(t) is made. General conclusions have been derived from the comparison.
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