Abstract

Several methods of deep desulfurization in alumina production process were studied, and the costs of these methods were compared. It is found that most of the S2−removed by adding sodium nitrate or hydrogen peroxide in digestion process, and in this way the effect of S2− on alumina product quality is eliminated. However, the removal efficiency of S2O32− in sodium aluminate solution is very low by this method. Both S2− and S2O32− in sodium aluminate solution can be removed completely by wet oxidation method in digestion process. The cost of desulfurization by wet oxidation is lower than by adding sodium nitrate or hydrogen peroxide. The results of this research reveal that wet oxidation is an economical and feasible method for the removal of sulfur in alumina production process to improve alumina quality, and provide valuable guidelines for alumina production by high-sulfur bauxite.

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