Abstract

The photoelectron transfer from zinc porphyrin or chlorophyll to various dialkyl viologens occurs from the triplet state of the sensitizer in oil-in-water cetyltrimethylammonium chloride (CTAC) micelles and in water-in-oil Aerosol OT micelles. The charge separation following the photoelectron transfer is due to the entrance of reduced viologens into the micellar core in oil-in-water CTAC micelles and to bimolecular exchange between water pools in reverse micelles

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