A Comparison of the Forward and Back Photoelectron Transfer in Direct and Reverse Micelles

M P Pileni,P Brochette,B Lerebours Pigeonnière

doi:10.1007/978-94-009-4582-1_20

A Comparison of the Forward and Back Photoelectron Transfer in Direct and Reverse Micelles

M P Pileni, P Brochette + Show 1 more

https://doi.org/10.1007/978-94-009-4582-1_20

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Publication Date: Jan 1, 1986

Citations: 1

Affiliation: Saclay Nuclear Research Centre, Laboratoire de Chimie Physique

#Direct Micelles #Reverse Micelles + Show 8 more

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Abstract

The photoelectron transfer from porphyrins to various viologens occurs from the triplet state of the sensitizer in oil in water cetyltrimethylammonium chloride (CTAC) and in water in oil Aerosol OT micelles. In direct micelles, DM, very important charge separation is due to the entrance of reduced viologen into the micellar core. In reverse micelles, RM, the charge separation is strongly incrased by a difference in the mechanism between the forward and the back reaction.

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