Abstract

An acrylic pressure-sensitive adhesive (PSA) was synthesized in ethyl acetate at about 80 °C by the use of 2-ethylhexyl acrylate, ethyl acrylate, methyl acrylate and acrylic acid at presence of thermal radical initiator AIBN. The synthesized acrylic PSA was crosslinked at relatively low temperatures at about 110–125 °C using thermal crosslinkers selected from melamine-formaldehyde resins and benzoguanamine resins. The crosslinking process runs between carboxylic groups of acrylic PSA and reactive groups from investigated amine resins. The choice of suitable thermal reactive crosslinkers has significant and relevant influence at presence of organic acid catalysts on main performance of crosslinked PSA such as tack, peel adhesion and shear strength.

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