Abstract
The exchange charge model of crystal field was used to calculate the crystal field splitting of all Ni2+ energy levels (3d8 electron configuration) in three structurally similar crystals of CdCl2, CdBr2, and CdI2. The influence of the nature of the ligands and interionic distances on the values of the crystal field parameters and location of the split energy levels and relative intervals between them was identified. Comparison of the calculated energy levels with the experimental results available in the literature yielded good agreement.
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