Abstract

The numerical values of the logarithm of the infinite dilution activity coefficient, lnγ1∞, and excess partial molar excess enthalpy at infinite dilution, H1E,∞, calculated by Zhang and coworkers are not thermodynamically consistent with each other. The calculated values do not obey the standard thermodynamic relationship that the variation in lnγ1∞ with 1/T must be equal H1E,∞ divided by the universal gas constant.

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