Combination of multiple routes to enhance DSSC performance: Flower-like structure of SnO2 as photoanode and modification with Ag nanoparticle

Abstract

SnO2 is an attractive photoanode material for dye-sensitized solar cells (DSSCs), but it has many drawbacks and needs to be modified. In this study, flower-like SnO2 particles are firstly prepared by a simple one-step hydrothermal synthesis method respectively, and the effect of hydrothermal reaction time on the growth of the particles is explored. The morphological and structural characterisation reveals that the flower-like particles have a larger specific surface area can provide more adsorption sites for dye molecules and are more suitable for photoanode materials. Then the optimal flower-like SnO2 particles are selected to prepare the photoanode, which is also modified with different concentrations of Ag nanoparticles to successfully introduce the localized surface plasmon resonance (LSPR) effect, and the optimal modification concentration is explored. Conformal characterisation, dye adsorption and light absorption tests revealed that the modification of Ag nanoparticles not only optimises the photoanode conformal structure and improves the dye adsorption, but also works in conjunction with the LSPR effect to improve the light absorption and utilisation, thus increasing the cell efficiency. Many cell performances of DSSC are also greatly improved due to the above work, and the optimal cell performance of DSSC is achieved when the Ag nanoparticles doping concentration is 0.03 M. Compared with the pure flower-like SnO2-based photoanode DSSC, the short-circuit current density of the best Ag nanoparticle-modified DSSC is enhanced by 28.56% to 15.80 mA/cm2, and its efficiency is improved by 20.82%–5.92%.