Abstract

Polystyrene (PS)-polyisoprene (PI) diblock copolymers dissolved in n-decane aggregate into spherical micelles with a PS core and a corona of tethered PI chains. The PI corona may be considered as a brush on the surface of a sphere or as the outer part of a many-armed polymer star. The thermal density fluctuations of the PI corona have been observed by neutron spin-echo spectroscopy. The peculiar multi-decay time relaxation behavior can be described remarkably well by a model based on an idea of de Gennes for treating the corona as a semidilute polymer solution with varying concentration profile.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.