Abstract
Doping a Cr7Zn molecular nanomagnet into a diamagnetic and isostructural host allows pulsed X-band EPR on single crystals, including relaxation and nutation experiments on the S = 3/2 ground state.
Highlights
Doping a Cr7Zn molecular nanomagnet into a diamagnetic and isostructural host allows pulsed X-band EPR on single crystals, including relaxation and nutation experiments on the S = 3/2 ground state
The metal ions in each molecule define a planar octagon, with each edge bridged by a fluoride and two pivalates, giving a complex anion which is centred on a Me2NH2+ cation (Fig. S1, Electronic supplementary information (ESI)†)
Cr7Zn@Ga7Zn crystallises in the tetragonal I4 space group (ESI†), with the molecules lying on the C4 axis such that the M07Zn rings are in the crystal ab plane (Fig. 1)
Summary
Coherent electron spin manipulation in a dilute oriented ensemble of molecular nanomagnets: pulsed EPR on doped single crystals† Doping a Cr7Zn molecular nanomagnet into a diamagnetic and isostructural host allows pulsed X-band EPR on single crystals, including relaxation and nutation experiments on the S = 3/2 ground state.
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