Coercivity behavior in [formula omitted] system as function of the microstructureevolution

Abstract

Magnetic measurements, X-ray diffraction and scanning electron microscopy (SEM) experiments were carried out in the as-cast Gd(Co1−xCux)5 samples with different Co/Cu content. Already in the as cast state, this system shows high coercive field for x=0.3 and a magnetization driven by nucleation of reversal domain. SEM micrograph and microanalysis show possible spinodal decomposition in the as-cast state, hence regions with different Co/Cu-content are observed, while the Gd-content almost does not change. High resolution X-ray diffraction patterns show a main CaCu5-type structure with traces of a secondary phase and distorted peak profiles as function of the Cu content. The evolution of the microstructure is discussed in relation with the Cu incorporation into the CaCu5-type structure. The Cu addition avoids the formation of the 2:7 phase within the 1:5 matrix, favoring the formation of a more homogeneous Gd(Co,Cu)5 phase. The relation between the observed microstructure and the magnetic behavior is also discussed.