Abstract

Abstract New complexes of Co(II), Ni(II) and Cu(II) with Schiff bases obtained by the condensation of acetyl-acetone with glycine, β-alanine, L-leucine and DL-methionine have been synthesised and characterized by elemental analysis, molar conductance, magnetic, electronic, infrared spectral and thermalgravimetric analysis measurements. These complexes are non-electrolytes. Magnetic and spectral data indicate the Cu(II) complexes to be square planar and the Ni(II) and Co(II) complexes to be octahedral. All the Schiff bases coordinate through ONO donor sets derived from the carboxyl, imino and acetoxy groups:

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