Coal Bottom Ash as Sorbing Material for Fe(II), Cu(II), Mn(II), and Zn(II) Removal from Aqueous Solutions

Abstract

Investigations were undertaken to study sorption of heavy metal ions from aqueous solution onto coal bottom ash. X-ray diffraction analysis of coal bottom ash indicated presence of feldspar (KAlSi3O8–NaAlSi3O8–CaAl2Si2O8), mullite (Al6Si2O13), and magnetite (Fe2+Fe3+ 2O4). Toxicity characteristics leaching procedure (TCLP) revealed that heavy metal ions such as Fe(II), Fe(III), Mn(II), Cu(II), Zn(II), As(III), As(V), Pb(II), and Cd(II) could be leached out from coal bottom ash. Continuous column test with the bottom ash showed negligible heavy metal ion leach-out at pH 6.0, although at pH 4.2 some heavy metal ion leaching, mainly of Mn(II), was observed. Batch sorption studies with individual heavy metal ions (Fe(II), Cu(II), Zn(II) and Mn(II)) revealed that the heavy metal ion sorption onto coal bottom ash could be described by pseudo-second-order kinetics. Sorption isotherm studies revealed that Langmuir isotherm could adequately describe the heavy metal ion sorption onto coal bottom ash with maximum adsorption capacity (q m) ranging from 1.00 to 25.00 mg/g for various heavy metal ions. Removal of heavy metal ions by coal bottom ash is attributed to both adsorption and hydroxide precipitation of heavy metals due to the presence of different oxides (i.e., SiO2, Al2O3, Fe2O3, CaO) in coal bottom ash.