Abstract
Several complexes containing the ligands (L) thimorpholin-3-one or thiazolidine-2-thione of general formula MLnXm are reported {M = Zn, Cd, Co, or Ni; X =[SO4]2–(m= 1) and [NO3]–(m= 2); n= 2, 4, or 6} The complexes have been characterized by chemical analyses, ligand-field spectra, magnetic-susceptibility measurements, molecular conductance, and vibrational spectra (conventional and far infrared). Assignments for the metal–ligand modes have also been made. By use or i.r. spectroscopy it is possible to distinguish whether the anions present are co-ordinated to the transition metal ion or are present as free ions. Spectroscopic parameters for the cobalt and nickel complexes are compared with similar chromophores containing sulphur, oxygen, and nitrogen donor atoms. The evidence suggests that the zinc and cadmium complexes are tetrahedral, whereas the cobalt(II) and nickel(II) complexes are tetrahedral or octahedral.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of the Chemical Society, Dalton Transactions
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
