Abstract
Infrared spectra have been obtained over the range 70–4000 cm.–1 for complexes of the types InX3L3 and InX3L2, where X = Cl, Br, and I and L = donor ligand. The evidence indicates a pentaco-ordinate monomeric structure for the InX3L2 series [L = Ph3PO, Ph3P, or ½(Ph2P·C2H4·PPh2)] in the solid state, the trans-octahedral form for InX3(dimethyl sulphoxide)3, and the cis-octahedral structure for InX3py3.
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More From: Journal of the Chemical Society A: Inorganic, Physical, Theoretical
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