Abstract

Studies of vibrational energy transfer in N 2O over the temperature range from −41° to +92°C have been performed by monitoring the 4.5 μm fluorescence decay from N 2O excited by a CO 2 laser. These data confirm the increase in deactivation probability with increasing temperature above room temperature, and exhibit a leveling off in cross section as temperature decreases below room temperature. In addition, measurements on 14N 14NO by the same technique show a significantly smaller cross-section than for 14N 14NO.

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