Abstract
Clustering and continuum percolation in dipolar fluids are studied through Monte Carlo simulation and connectedness theory with an emphasis on the effect of the dipole-dipole interactions on the size and shape of the clusters and on the threshold percolation density. Two simple models for the dipolar fluid are considered: (i) a system of hard spheres with an embedded point dipole and (ii) a related system of hard spheres in which the dipole-dipole forces are replaced by an angular-averaged dipolar potential. A first-order perturbation theory (for the first model) and the connectedness version of the Percus-Yevick integral equation (for the second one) are used to describe clustering and percolation, and their results are compared with the corresponding Monte Carlo data. Our results show that clusters become larger in size and acquire a stronger mean dipolar moment when the particles' dipolar moments are increased. Far from the percolation transition, the clusters are nonspherical, the eccentricity being favored by the energetics of dipolar orientation. Furthermore, they reveal that larger dipolar strengths imply smaller percolation densities.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Physical review. A, Atomic, molecular, and optical physics
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.