Abstract
The reaction of Ag 2O and carboxylate ligands in ammonium solution results in three coordination polymers, [Ag(fbc)] n 1, [Ag 2(cpd)] n 2 and [Ag 2(idc)] n 3, where fbcH is 4-fluorobenzoic acid, cpdH 2 is cyclopentane-1,1-dicarboxylic acid and idcH 2 is iminodiacetic acid. The X-ray crystal structural analysis indicates that compounds 1 and 2 are two-dimensional frameworks and 3 is a three-dimensional framework. All the three complexes show clear Ag–Ag bonds and high cytotoxicity properties to normal cells and carcinoma cells. ▪
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