Cis-Dichloro complexes of NiII, PdII, and PtII derived from 2-pyridylmethyl-N-substituted imines

Abstract

Synthesis and structural characterization of cis-dichlorocomplexes derived from 2-pyridylmethyl-N-methylimine (1), 2-pyridylmethyl-N-ethylimine (2), and 2-pyridylmethyl-N-(2-bromophenyl)imine (3) of general formula [MII{(C5H4N)–C(H)NR}nCl2] {M=Ni, Pd, Pt; R=Me, Et, –(2-Br–C6H4); n=1, 2} are described. Paramagnetic complexes of NiII (1a–3a) were identified by elemental analyses, vibrational spectroscopy and for 2a and 3a, by electronic spectroscopy; the complexes of PdII (1b–3b) and PtII (1c–3c) were characterized by elemental analyses, vibrational spectroscopy and NMR. X-ray molecular structures of 1a, 2a, 1b–3b, 2c and 3c displayed a bidentate coordination mode of the N-substituted pyridylimines (1–3) towards the metallic atoms with the formation of five-membered chelate rings and the chlorine atoms in a cis coordination. In 1a and 2a a distorted octahedral local geometry around the nickel atom was observed, whereas a distorted square planar local geometry around the palladium and platinum atoms in the compounds 1b–3b, 2c and 3c was displayed.