Abstract
The structure of the title compound, [CrCl2(C2H6OS)4]Cl·C2H6OS, consists of a CrIII ion coordinated by four O atoms of dimethyl sulfoxide (DMSO) ligands and two chloride ions in cis positions, forming a distorted CrCl2O4 octahedron. An isolated Cl− counter-anion and a positionally disordered DMSO molecule [occupancy ratio 0.654 (4):0.346 (4)] are also present. In the structure, the complex cations interact with the Cl− counter-anions and the DMSO solvent molecules via weak C—H⋯Cl and C—H⋯O interactions, forming a three-dimensional network.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
