Abstract
In the mononuclear title complex, [Zn(C10H8N2)2(C2H6OS)2](C24H20B)2·C2H6OS, the ZnII ion is coordinated by four N atoms of two bidentate 2,2′-bipyridine molecules and by the O atoms of two cis-disposed dimethyl sulfoxide molecules in a distorted octahedral geometry. The S atom and the methyl groups of one of the coordinated dimethyl sulfoxide molecules are disordered in a 0.509 (2):0.491 (2) ratio. The crystal packing is stabilized by C—H⋯O hydrogen bonds between the dimethyl sulfoxide solvent molecules and tetraphenylborate anions.
Highlights
In the mononuclear title complex, [Zn(C10H8N2)2(C2H6OS)2](C24H20B)2C2H6OS, the ZnII ion is coordinated by four N atoms of two bidentate 2,20 -bipyridine molecules and by the O atoms of two cis-disposed dimethyl sulfoxide molecules in a distorted octahedral geometry
The crystal packing is stabilized by C—H O hydrogen bonds between the dimethyl sulfoxide solvent molecules and tetraphenylborate anions
One of the coordinated dimethyl sulfoxide (DMSO) molecules was found to be disordered over two positions, its sulfur and carbon atoms were refined with occupancy factors 0.502/0.498
Summary
National Taras Shevchenko University of Kyiv, Department of Chemistry, Volodymyrska Str. 64, 01601 Kyiv, Ukraine, bUniversity of Wrocław, Faculty of Chemistry, F. Joliot-Curie Str. 14, 50-383 Wrocław, Poland, and cKyiv National. University of Construction and Architecture, Department of Chemistry, Povitroflotsky
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