Abstract
In the mononuclear title complex, [Zn(C10H8N2)2(C2H6OS)2](C24H20B)2·C2H6OS, the ZnII ion is coordinated by four N atoms of two bidentate 2,2′-bipyridine molecules and by the O atoms of two cis-disposed dimethyl sulfoxide molecules in a distorted octahedral geometry. The S atom and the methyl groups of one of the coordinated dimethyl sulfoxide molecules are disordered in a 0.509 (2):0.491 (2) ratio. The crystal packing is stabilized by C—H⋯O hydrogen bonds between the dimethyl sulfoxide solvent molecules and tetraphenylborate anions.
Highlights
In the mononuclear title complex, [Zn(C10H8N2)2(C2H6OS)2](C24H20B)2C2H6OS, the ZnII ion is coordinated by four N atoms of two bidentate 2,20 -bipyridine molecules and by the O atoms of two cis-disposed dimethyl sulfoxide molecules in a distorted octahedral geometry
The crystal packing is stabilized by C—H O hydrogen bonds between the dimethyl sulfoxide solvent molecules and tetraphenylborate anions
One of the coordinated dimethyl sulfoxide (DMSO) molecules was found to be disordered over two positions, its sulfur and carbon atoms were refined with occupancy factors 0.502/0.498
Summary
National Taras Shevchenko University of Kyiv, Department of Chemistry, Volodymyrska Str. 64, 01601 Kyiv, Ukraine, bUniversity of Wrocław, Faculty of Chemistry, F. Joliot-Curie Str. 14, 50-383 Wrocław, Poland, and cKyiv National. University of Construction and Architecture, Department of Chemistry, Povitroflotsky
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.