Abstract
In the title compound, [Ni(C16H10N3O3)2(C5H5N)2], the NiII cation is in a distorted octahedral NiN4O2 coordination by two independent bidentate 1-[(4-nitrophenyl)diazenyl]-2-naphtholate anions and two pyridine ligands. C—H⋯O interactions between aromatic rings and the O atoms of the nitro substituents build up a two-dimensional supramolecular arrangement parallel to (100).
Highlights
Instituto de Quımica, Universidade Federal do Rio de Janeiro, Caixa Postal 68563, 21949-900 Rio de Janeiro, RJ, Brazil
C—H O interactions between aromatic rings and the O atoms of the nitro substituents build up a two-dimensional supramolecular arrangement parallel to (100)
X-ray diffraction measurements were performed in the Laboratório de Difração de Raios X at the Universidade
Summary
R factor = 0.039; wR factor = 0.090; data-to-parameter ratio = 12.8. In the title compound, [Ni(C16H10N3O3)2(C5H5N)2], the NiII cation is in a distorted octahedral NiN4O2 coordination by two independent bidentate 1-[(4-nitrophenyl)diazenyl]-2-naphtholate anions and two pyridine ligands. C—H O interactions between aromatic rings and the O atoms of the nitro substituents build up a two-dimensional supramolecular arrangement parallel to (100)
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