Cis-Bis[1,1-dibenzyl-3-(furan-2-ylcarbonyl)thioureato-κ2O,S]copper(II)

Hiram Pérez,Ana M Plutín,Cecilia C P Da Silva,Carlos A De Simone,Javier Ellena

doi:10.1107/s160053681101422x

Abstract

In the title compound, [Cu(C20H17N2O2S)2], the CuII atom is coordinated by the S and O atoms of two 1,1-dibenzyl-3-(furan-2-ylcarbonyl)thioureate ligands in a distorted square-planar geometry. The two O and two S atoms are mutually cis to each other. The Cu—S and Cu—O bond lengths lie within the ranges of those found in related structures. The dihedral angle between the planes of the two chelating rings is 26.15 (6)°.

Highlights

In the title compound, [Cu(C20H17N2O2S)2], the CuII atom is coordinated by the S and O atoms of two 1,1-dibenzyl-3(furan-2-ylcarbonyl)thioureate ligands in a distorted squareplanar geometry
The Cu—S and Cu—O bond lengths lie within the ranges of those found in related structures
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

Summary

Crystal data

ISSN 1600-5368 cis-Bis[1,1-dibenzyl-3-(furan-2-ylcarbonyl)thioureato-j2O,S]copper(II) Carlos A. de Simoneb and Javier Ellenab a Departamento de Quımica Inorgánica, Facultad de Quımica, Universidad de la Habana, Habana 10400, Cuba, bGrupo de Cristalogafia, Instituto de Fısica de São Carlos, Universidade de São Paulo, São Carlos, Brazil, and cLaboratorio de Sıntesis R factor = 0.049; wR factor = 0.122; data-to-parameter ratio = 16.1. In the title compound, [Cu(C20H17N2O2S)2], the CuII atom is coordinated by the S and O atoms of two 1,1-dibenzyl-3(furan-2-ylcarbonyl)thioureate ligands in a distorted squareplanar geometry. The two O and two S atoms are mutually cis to each other. The Cu—S and Cu—O bond lengths lie within the ranges of those found in related structures. The dihedral angle between the planes of the two chelating rings is 26.15 (6) .

Related literature

Data collection

Special details