Abstract
In the title compound, [Ni(C20H17N2O2S)2], the NiII atom is coordinated by the S and O atoms of two 1,1-dibenzyl-3-[(furan-2-yl)carbonyl]thioureate ligands in a distorted square-planar geometry. The two O and two S atoms are mutually cis to each other. The Ni—S and Ni—O bond lengths lie within the range of those found in related structures. The dihedral angle between the planes of the two chelating rings is 20.33 (6)°.
Highlights
In the title compound, [Ni(C20H17N2O2S)2], the NiII atom is coordinated by the S and O atoms of two 1,1-dibenzyl-3[(furan-2-yl)carbonyl]thioureate ligands in a distorted squareplanar geometry
The Ni—S and Ni—O bond lengths lie within the range of those found in related structures
The cell s.u.'s are taken into account individually in the estimation of s.u.'s in distances, angles and torsion angles; correlations between s.u.'s in cell parameters are only used when they are defined by crystal symmetry
Summary
ISSN 1600-5368 cis-Bis{1,1-dibenzyl-3-[(furan-2-yl)carbonyl]thioureato-j2O,S}nickel(II) Carlos A. de Simoneb and Javier Ellenab a Departamento de Quımica Inorgánica, Facultad de Quımica, Universidad de la Habana, Habana 10400, Cuba, bGrupo de Cristalogafia, Instituto de Fısica de São Carlos, Universidade de São Paulo, São Carlos, Brazil, and cLaboratorio de Sıntesis
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