Abstract
The thermodynamic properties of the glassy polyvinyltrimethylsilane (PVTMS) have been investigated by means of reverse gas chromatography. Values of the Flory-Huggins parameter in the range 25–230° were determined for systems of the types: polyvinyltrimethylsilane-hydrocarbons and polyvinyltrimethylsilane-alcohols. As the temperature rises the hydrocarbons become θ solvents for polyvinyltrimethylsilane, while the alcohols become good solvents.
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