Abstract
The title compound, [RuCl(C24H16N2)(C15H11N3)]PF6, consists of a monomeric RuII complex cation and a hexafluorophosphate anion. The coordination environment about the RuII atom is distorted octahedral, where the 2,2′:6′,2′′-terpyridine (terpy) ligand is coordinated in a meridional fashion, the 4,7-diphenyl-1,10-phenanthroline (dpphen) ligand is coordinated in a cis fashion and the Cl atom is trans to one of the dpphen N atoms. The Ru—N bond distances are in the range 1.956 (5)–2.096 (5) A and the Ru—Cl distance is 2.403 (2) A.
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