Abstract
In the title complex, [Co(C15H12N3O4)2Cl(C6H7N)], the CoIII ion is coordinated by two N atoms and two O atoms from two deprotonated Schiff base ligands, one N atom from a 4-methylpyridine ligand and one Cl atom, forming a distorted octahedral geometry. The CoIII ion is displaced by 0.038 (2) Å from the equatorial plane towards the axial Cl atom.
Highlights
In the title complex, [Co(C15H12N3O4)2Cl(C6H7N)], the CoIII ion is coordinated by two N atoms and two O atoms from two deprotonated Schiff base ligands, one N atom from a 4methylpyridine ligand and one Cl atom, forming a distorted octahedral geometry
The equatorial plane is defined by three donor atoms (O3, O7 and N3) from two hydrazine ligands and N7 atom from a 4-methylpyridine ligand, with an r.m.s. deviation of 0.0305 Å from the mean plane
The CoIII ion is displaced towards the axial Cl1 atom by 0.038 (2)Å from the equatorial plane
Summary
In the title complex, [Co(C15H12N3O4)2Cl(C6H7N)], the CoIII ion is coordinated by two N atoms and two O atoms from two deprotonated Schiff base ligands, one N atom from a 4methylpyridine ligand and one Cl atom, forming a distorted octahedral geometry. Absorption correction: multi-scan (ABSCOR; Higashi, 1995) Qiong-Jie Wu,a* Xiao-Hua Chen,b Jiang Jiang,a Bi-Qiong Fujian Normal University, Fuzhou, Fujian 350007, People’s Republic of Correspondence e-mail: wqiongj_jane@163.com In the title complex, [Co(C15H12N3O4)2Cl(C6H7N)], the CoIII
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